Synthesis of optically pure [60]fullerene e,e,e-tris adducts.

نویسندگان

  • Sebastiano Guerra
  • Franck Schillinger
  • David Sigwalt
  • Michel Holler
  • Jean-François Nierengarten
چکیده

The reaction of readily available optically active Si-tethered tris(malonates) with C60 gave easily separable diastereoisomers differing by the absolute configuration of the inherently chiral addition pattern on the fullerene core. The absolute configuration of the e,e,e addition pattern has been unambiguously determined using X-ray crystal structure analysis.

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Regioselective synthesis and zone selective deprotection of [60]fullerene tris-adducts with an e,e,e addition pattern.

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عنوان ژورنال:
  • Chemical communications

دوره 49 42  شماره 

صفحات  -

تاریخ انتشار 2013